Optimization of Electron Transfer Dissociation via Informed Selection of Reagents and Operating Parameters
نویسندگان
چکیده
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15 صفحه اولDistance dependence of through-bond electron transfer rates in electron-capture and electron-transfer dissociation
Ab initio electronic structure calculations on model cations containing a disulfide linkage and a protonated amine site are carried out to examine ow the rate of electron transfer from a Rydberg orbital on the amine site to the S S * orbital depends upon the distance between these two rbitals. These simulations are relevant to both electron-capture and electron-transfer dissociation mass spectr...
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ژورنال
عنوان ژورنال: Analytical Chemistry
سال: 2012
ISSN: 0003-2700,1520-6882
DOI: 10.1021/ac202807h